Getting Started with OpenVMS: A Guide for New Users (HP Technologies)
The OpenVMS frequently asked questions (FAQs) list is currently archived at these locations, among others:
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http://www.openvms.compaq.com/
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ftp://rtfm.mit.edu/pub/usenet/comp.os.vms/
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ftp://www.faqs.org/
The recent merger of Compaq and Hewlett-Packard may result in a change to the first link above.